A face can be divide into multiple faces with FreeCAD. For example, with this function, you can set load condition on a part of the single face in physical simulation on FEM workbench.
Select [View]-[Workbench]-[Sketcher] menu to switch workbench to sketcher workbench.
On 3D view, click a face that you want to divide. Make sketch plane on selected face and draw the face region as sketch.
Select [View]-[Workbench]-[Part] menu to switch workbench to part workbench.
In model tree, first select the shape that has the face to be divided (In the example, cuboid), and then select the sketch defining face region (In the example, sketch defining a circle). You can select multiple item by clicking them with Ctrl key.
Execute "Slice to compound" to create a face region on the plane from the sketch.
The face region like this can be used in simulation in FEM workbench. Forexample, you can set load condition at a part of single plane in condition settings.